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4-CL-PVP CRYSTAL is classed as being a substituted cathinone. The substituted cathinones are multitudinous and diverse. Their defining capabilities can be a phenethylamine spine having a ketone within the beta position and an alkyl substituent on the alpha placement over the carbon adjacent to the nitrogen.
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As chlorine is highly electrophilic the profile of electrostatic charge all over the molecule are going to be altered, forever or negative. Sterically it will also alter binding, but yet again substitutions during the para situation have been well tolerated in other cathinones such as four MMC.
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